1-(4-Methylbenzoyl)-3-{2-[3-(4-methylbenzoyl)thioureido]phenyl}thiourea
نویسندگان
چکیده
In the title compound, C(24)H(22)N(4)O(2)S(2), the dihedral angles formed by the thio-ureido groups with the attached benzene ring are 43.81 (13) and 75.25 (13)°. The dihedral angle between the thio-ureido groups is 85.48 (10)°. The mol-ecule is stabilized by intra-molecular N-H⋯S, N-H⋯O and C-H⋯S hydrogen bonds. In the crystal, molecules are linked by intermolecular N-H⋯S hydrogen bonds together with C-H⋯π inter-actions.
منابع مشابه
Ethyl 4-[3-(2-methylbenzoyl)thioureido]benzoate
The mol-ecular conformation of the title compound, C(18)H(18)N(2)O(3)S, is stabilized by an intra-molecular N-H⋯O hydrogen bond. The crystal packing shows centrosymmetric dimers connected by N-H⋯S hydrogen bonds. The terminal eth-oxy substituents are statistically disordered [occupancy ratio 0.527 (5):0.473 (5)].
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In the title compound, C(27)H(20)O(2), the central benzene ring makes dihedral angles of 64.86 (7) and 70.35 (7)° with the methyl-substituted ring and the biphenyl ring system, respectively. The crystal packing is stabilized by inter-molecular C-H⋯O inter-actions, which link the mol-ecules into chains parallel to the b axis.
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In the title compound, C(19)H(17)N(3)O(2), the dihedral angles between the pyrimidine ring and the two benzene rings are 34.87 (12) (for the directly-bonded ring) and 69.57 (12)°. An intra-molecular N-H⋯O hydrogen bond occurs. The crystal packing features inter-molecular N-H⋯O hydrogen bonds.
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In the title compound, C(15)H(12)O(3)·H(2)O, the two rings are oriented at a dihedral angle of 69.12 (3)°. In the crystal structure, intermolecular O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional framework.
متن کامل7-Hydroxy-4-methyl-8-(3-methylbenzoyl)-2H-chromen-2-one ethanol monosolvate
In the title compound, C(18)H(14)O(4)·C(2)H(6)O, the coumarin ring system is approximately planar with a maximum deviation of 0.037 (3) Å and is nearly perpendicular to the benzene ring, making a dihedral angle of 86.55 (9)°. In the crystal, mol-ecules are linked by classical O-H⋯O hydrogen bonds and weak C-H⋯O inter-actions.
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